Has the use of nuclear weapons been threatened?

Has the use of nuclear weapons been threatened?
Yes, here are a few examples in history of such threats:

NUCLEAR WEAPON CRISES 1946 – 1985

Incident Year Length of Crisis Threat By Weapons Held by US Weapons Held by USSR
IRAN I 1946 One day USA 40 0
YUGOSLAVIA 1946 One day USA 40 0
BERLIN 1 1948 15 months USA 120 0
KOREA 1950 36 months USA 400 ?
VIETNAM 1 1954 3 months USA 1200 ?
CHINA 1 1954 8 months USA 1200 ?
SUEZ 1956 7 days USSR/USA 2100 60
CHINA 2 1958 2 months USA 3000 110
BERLIN 2 1959 4 months USA 3200 175
BERLIN 3 1961 4 months USA 3600 240
CUBA 1962 2 weeks USSR/USA 3900 300
VIETNAM 2 1969 3 months USA 4000 1400
JORDAN 1970 2 weeks USA 4000 1800
ISRAEL 1973 19 days USA 6800 2200
IRAN 2 1980 6 months USA 10312 6846

Source:  David Morgan, VANA